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71.
E.T. Lilleodden J.A. Zimmerman W.D. Nix 《Journal of the mechanics and physics of solids》2003,51(5):901-920
Nanoindentation experiments have shown that microstructural inhomogeneities across the surface of gold thin films lead to position-dependent nanoindentation behavior [Phys. Rev. B (2002), to be submitted]. The rationale for such behavior was based on the availability of dislocation sources at the grain boundary for initiating plasticity. In order to verify or refute this theory, a computational approach has been pursued. Here, a simulation study of the initial stages of indentation using the embedded atom method (EAM) is presented. First, the principles of the EAM are given, and a comparison is made between atomistic simulations and continuum models for elastic deformation. Then, the mechanism of dislocation nucleation in single crystalline gold is analyzed, and the effects of elastic anisotropy are considered. Finally, a systematic study of the indentation response in the proximity of a high angle, high sigma (low symmetry) grain boundary is presented; indentation behavior is simulated for varying indenter positions relative to the boundary. The results indicate that high angle grain boundaries are a ready source of dislocations in indentation-induced deformation. 相似文献
72.
The paper deals with the estimation of the pressure distribution, the shape of contact and the friction force at the interface of a flat soft elastic solid moving on a rigid half-space with a slightly wavy surface. In this case an unsymmetrical contact is considered and justified with the adhesion hysteresis. For soft solids as rubber and polymers the friction originates mainly from two different contributions: the internal friction due to the viscoelastic properties of the bulk and the adhesive processes at the interface of the two solids. In the paper the authors focus on the latter contribution to friction. It is known, indeed, that for soft solids, as rubber, the adhesion hysteresis is, at least qualitatively, related to friction: the larger the adhesion hysteresis the larger the friction. Several mechanisms may govern the adhesion hysteresis, such as the interdigitation process between the polymer chains, the local small-scale viscoelasticity or the local elastic instabilities. In the paper the authors propose a model to link, from the continuum mechanics point of view, the friction to the adhesion hysteresis. A simple one-length scale roughness model is considered having a sinusoidal profile. For partial contact conditions the detached zone is taken to be a mode I propagating crack. Due to the adhesion hysteresis, the crack is affected by two different values of the strain energy release rate at the advancing and receding edges respectively. As a result, an unsymmetrical contact and a friction force arise. Additionally, the stability of the equilibrium configurations is discussed and the adherence force for jumping out of contact and the critical load for snapping into full contact are estimated. 相似文献
73.
We consider a fully discrete scheme for a quasistatic frictional contact problem between a viscoelastic body and an obstacle. The contact is bilateral, the friction is modeled with Tresca's law and the behavior of the material is described with a viscoelastic constitutive law with long memory. We state an existence and uniqueness result for the discrete solution, followed by error estimate results. Then, we present numerical simulations in the study of a two-dimensional test example. To cite this article: Á. Rodríguez-Arós et al., C. R. Mecanique 334 (2006). 相似文献
74.
采用“基于角度度量的多变量回归方法”对维纶和腈纶混纺纤维各组分含量进行检测,并与直接用偏最小二乘法(PLS)对混和纤维的预测结果作对比。实验结果显示,PLS法对维纶和腈纶预测值与实际值的线性相关系数r均为0.9457,标准偏差为6.0906,均方根误差为6.9948。角度度量法对维纶预测值与实际值的线性相关系数r为0.9990,标准偏差为0.8929,均方根误差为2.1896;对腈纶预测值与实际值的线性相关系数r为0.9928,标准偏差为2.1896,均方根误差为3.9493。实验证明,角度度量法比PLS法更能准确表达定量关系,角度度量法可以显著降低分析操作对环境的要求,满足了近红外光谱在混纺纤维定量分析上的要求。 相似文献
75.
Arvind K. Gathania 《Liquid crystals》2013,40(7):773-776
Critical behaviour of the order parameters has been investigated in the ferroelectric liquid crystal mixture ZLI‐3654 in a 7.5 µm thick planar cell. The temperature dependence of the primary (tilt angle) and secondary (spontaneous polarisation) order parameters is considered. The critical exponent (β) has been evaluated from the fitting of the temperature dependence of the experimental data for both tilt angle and spontaneous polarisation. Experimental results are compared with the predictions of the de Gennes and Landau models. 相似文献
76.
In order to ascertain the effect of a donor monomer, vinyl acetate (VAc), on the graft copolymerization of acceptor monomers, ethyl acrylate (EA) and butyl acrylate (BA), grafting of mixed vinyl monomers (EA + VAc) and (BA + VAc) was carried out on Himachali wool in aqueous medium using ceric ammonium nitrate (CAN) as a redox initiator. Graft copolymerization was carried out at different temperatures for various reaction periods. Percent grafting and percent efficiency were determined as functions of 1) concentration of mixed vinyl monomers, 2) concentration of CAN, 3) concentration of HNO3 4) temperature, and 5) reaction time. VAc, the donor monomer, was found to decrease percent grafting of EA and BA onto wool. 相似文献
77.
Abstract The family Anacardiaceae consists of 76 genera and about 600 species. A comparison of the species of Anacardiaceae is discussed with special emphasis on the importance of the exudates, the so-called sap, for their importance as lacquer to produce lacquer ware. Many exudates are poisonous. The individual chemical compounds which constitute the active ingredients of the oleoresin part of the sap and their function are described based on space-filling molecular models. Emphasis is also given to the organic components of lacquer trees of the South East Asian region, which is compared to other species of the Anacardiaceae family. 相似文献
78.
桥小脑角区(CPA)肿瘤的精准分割在手术治疗、放疗中有重要影响,本文结合更快速区域卷积神经网络(Faster-RCNN)和水平集(Level-Set)方法对CPA肿瘤的自动分割进行了研究.首先,采集317名CPA肿瘤患者的T1WI-SE序列磁共振图像,使用基于Faster-RCNN主干网络VGG16提取特征,结合区域建议网络(RPN)进行学习训练,建立带有CPA肿瘤位置信息的定位模型,再应用Level-Set对肿瘤进行精准分割.本文对比了不同CPA肿瘤区域勾画范围对分割结果产生的影响,并以精确率、召回率、均值平均精度值(mAP)和戴斯系数(Dice系数)等指标评估了模型定位和分割的性能.实验结果表明,结合Faster-RCNN和Level-Set建立的模型能更有效对CPA肿瘤进行精准分割,减轻临床医生的负担,并提升治疗效果. 相似文献
79.
Patrícia Santiago de Oliveira Patricio Iaci Miranda Pereira Natália Cristina Ferreira da Silva Eliane Ayres Fabiano Vargas Pereira Rodrigo Lambert Oréfice 《European Polymer Journal》2013
Polyurethane waterborne synthesis was performed using a two-step method, commonly referred to as a prepolymer method. Nanocomposites based on waterborne polyurethane and cellulose nanocrystals were prepared by the prepolymer method by altering the mode and step in which the nanofillers were incorporated during the polyurethane formation. The morphology, structural, thermal, and mechanical properties of the resulting nanocomposite films were evaluated by Fourier transform infrared spectroscopy (FTIR), small angle X-ray scattering (SAXS), scanning electron microscopy (SEM), and tensile tests. FTIR results indicated that the degree of interaction between the nanofillers and the WPU through hydrogen bonds could be controlled by the method of cellulose nanocrystal incorporation. Data obtained from SAXS experiments showed that the cellulose nanocrystals as well as the step of the reaction in which they are added influenced the morphology of the polyurethane. The reinforcing effect of CNCs on the nanocomposites depends on their morphology. 相似文献
80.
Polyamide 12 (PA12) is used in a variety of applications when low moisture absorption, good dimensional stability, and toughness are required. Polyamide 12 is one of the polymers most frequently employed to fabricate angioplasty balloon catheters; however, its high hydrophobicity and chemical inertness require the application of coatings to make its surface more hydrophilic and biocompatible. In this work, an alternative method, based on the photochemical reaction of PA12 with a hydrophilic aromatic azide, was developed. Static and dynamic contact angle measurements evidenced that the surface modification process was able to improve PA12 wettability and that the effects were retained even after 12 months from surface treatment. Polyamide 12 modification resulted in an increase of its surface free energy, as evaluated by the van Oss, Good, and Chaudhury method. X‐ray photoelectron spectroscopy confirmed the presence of the aromatic azide on PA12 surface. Finally, compliance tests showed that the modification process did not reduce the mechanical performance of balloons. 相似文献